Análisis sistemático de una metodología para escalado de reactores fotoquímicos heterogéneos basado en métodos matemáticos

Systematic analysis of a methodology for scaling up heterogeneous photochemical reactors based on mathematical methods

Contenido principal del artículo

Yineth Paola Velásquez Figueroa

Resumen

Se presenta un análisis sistemático para una metodología de escalamiento de reactores fotocatalíticos heterogéneos basada en modelos matemáticos. Se disgregó y explicó de manera detallada las etapas para el adecuado modelado matemático, simulación y cambio de escala de reactores fotoquímicos que usan semiconductores y radiación solar natural para su operación. Se encontró que los fundamentos de esta estructura se soportan en cuatro componentes fundamentales de los procesos de fotodegradación heterogénea: el sistema reactivo, el semiconductor, la fuente de radiación, y la geometría o tipo de reactor, tanto para su formulación como para la solución. El acoplamiento lógico de estos elementos garantiza una adecuada estructuración de ecuaciones para transferir datos de escala laboratorio a aplicaciones de planta piloto e incluso comerciales.

Palabras clave:

Descargas

Los datos de descargas todavía no están disponibles.

Detalles del artículo

Biografía del autor/a (VER)

Yineth Paola Velásquez Figueroa, Universidad Nacional Abierta y a Distancia

Universidad Nacional Abierta y a Distancia, Escuela de Ciencias Básicas e Ingeniería, Cartagena, Colombia

Referencias (VER)

O. Alfano, A. Cassano, “Photoreactor Modeling: Applications to Advanced Oxidation Processes,” Int. J. Chem. React. Eng., vol. 6, no. 2, pp. 1-20, 2008.

O. Alfano, A. Cassano, “Reaction engineering of suspended solid heterogeneous photocatalytic reactors,” Catal. Today, vol. 58, pp. 167-197, 2000.

D. Wang, M. A. Mueses, J.A. Colina-Márquez, F. Machuca-Martínez, I. Grčić, Rodrigo Peralta Muniz Moreira, G. Li Puma, “Engineering and engineering modeling perspectives on photocatalytic reactors for water treatment,” Water Res., vol. 202, 117421, Sep. 2021, DOI: https://doi.org/10.1016/j.watres.2021.117421

M. A. Mueses, J.A. Colina-Márquez, F. Machuca-Martínez, G. Li Puma, "Recent advances on modeling of solar heterogeneous photocatalytic reactors applied for degradation of pharmaceuticals and emerging organic contaminants in water," Curr. Opin. Green Sustain, vol. 30, 100486, Aug. 2021, DOI: https://doi.org/10.1016/j.cogsc.2021.100486

M. A. Mueses, F. Machuca-Martínez, G. Li Puma, "Effective quantum yield and reaction rate model for evaluation of photocatalytic degradation of water contaminants in heterogeneous pilot-scale solar photoreactors," Chem. Eng. J., vol. 215-216, pp. 937-947, Jan. 2013, DOI: https://doi.org/10.1016/j.cej.2012.11.076

G.M. Hincapié-Mejia, G. Peñuela, M.A. Mueses, “Evaluation of a helicoidal flux photoreactor applied in the dicloxacillin degradation by UV-C/H2O2 and UV-A/photo-Fenton including the effect of photon absorption,” Results Eng., vol. 15, 100519, Sep. 2022, DOI: https://doi.org/10.1016/j.rineng.2022.100519

F. Machuca-Martínez, J.A. Colina-Márquez, M.A. Mueses, “Determination of quantum yield in a heterogeneous photocatalytic system using a fitting-parameters model,” J. Adv. Oxid. Technol., vol. 11, no. 1, pp. 42-48, 2008.

R. Acosta-Herazo, P. Valadés-Pelayo, M.A. Mueses, M.H. Pinzón-Cardenas, C. Arancibia-Bulnes, F. Machuca-Martínez, “An optical and energy absorption analysis of the solar compound parabolic collector photoreactor (CPCP): The impact of the radiation distribution on its optimization,” Chem. Eng. J., 395, 125065, Sep. 2020, DOI: https://doi.org/10.1016/j.cej.2020.125065

C. Zalazar, R. Romero, C. Martin, A. Cassano, “Photocatalytic intrinsic reaction kinetics I: Mineralization of dichloroacetic acid,” Chem. Eng. Sci., vol. 60, pp. 5240-5254, 2005.

M. Altamar-Licona, R. Merlano-Castilla, J. A. Colina-Márquez, “Comparison of the adjustment of mathematical models in the mineralization of commercial paracetamol in a solar photocatalytic reactor type CPC at pilot scale,” Ing-Nova., vol 1, no. 2, pp. 152-157, Jul. 2022. DOI: https://doi.org/10.32997/rin-2022-3999

M. Satuf, R. Brandi, A. Cassano, O. Alfano, “Photocatalytic degradation of 4-chlorophenol: A kinetic study,” Appl. Catal., B, vol. 82, pp. 37-49, 2008.

J. Marugán, R. Van Grieken, A. Cassano, O. Alfano, “Intrinsic kinetic modeling with explicit radiation absorption effects of the photocatalytic oxidation of cyanide with TiO2 and silica-supported TiO2 suspensions,” Appl. Catal., B., vol. 85, pp. 48-60, 2008.

M. Satuf, R. Brandi, A. Cassano, O. Alfano, “Scaling-up of slurry reactors for the photocatalytic degradation of 4-chlorophenol,” Catal. Today, vol. 129, pp. 110-117, 2007.

J. Colina-Márquez, F. Machuca-Martínez, G. Li Puma, “Radiation absorption and optimization of solar photocatalytic reactors for environmental applications,” Environ. Sci. Technol., vol. 44, pp. 5112-5120, 2010.

J. Colina-Márquez, F. Machuca-Martínez, G. Li Puma, “Photocatalytic mineralization of commercial herbicides in a pilot-scale solar CPC reactor: Photoreactor modeling and reaction kinetics constants independent of radiation field, Environ. Sci. Technol., vol. 43, pp. 8953-8960, 2009.

G. Camera-Roda, F. Santarelli, “A radiation approach to the design of Photocatalytic Reactor,” Ind. Eng. Chem. Res., vol. 46, pp. 7637-7644, 2007.

A. Yañez, M. Quiñonez, A. Ramírez, S. Gaona, “Diseño, construcción y puesta a prueba de un reactor fotocatalítico de radiación solar simulada,” Ing-Nova., vol. 1, no. 2, pp. 180-194, Jul. 2022. https://doi.org/10.32997/rin-2022-4003

C. Zalazar, M. Labas, C. Martin, R. Brandi, O. Alfano, A. Cassano, “The extended use of actinometry in the interpretation of photochemical reaction engineering data,” Chem. Eng. J., vol. 109, pp. 67-81, 2005.

D. Ballari, O. Alfano, A. Cassano, “Photocatalytic degradation of dichloroacetic acid: A kinetic study with a mechanistically based reaction model,” Ind. Eng. Chem. Res., vol. 48, pp. 1847-1858, 2009.

M. Satuf, R. Brandi, A. Cassano, O. Alfano, “Quantum efficiencies of 4-chlorophenol photocatalytic degradation and mineralization in a well-mixed slurry reactor,” Ind. Eng. Chem. Res., vol. 46, pp. 43-51, 2007.

A. Brucato, A. Cassano, F. Grisafi, G. Montante, L. Rizzuti, G. Vella, “Estimating radiant fields in flat heterogeneous photoreactors by the six-flux model,” AIChE J., vol. 52, no. 11, pp. 3882-3890, 2006.

J. Duderstadt, R. Martin, Transport theory, New York, Wiley, 1979, pp. 421-442.

J. Marugán, R. van Grieken, O. Alfano, A. Cassano, “Comparison of empirical and kinetic modeling of the photocatalytic oxidation of cyanide,” Int. J. Chem. React. Eng., vol. 5, A89, pp. 1-9, 2007.

D. Marquardt, “An algorithm for least-squares estimation of nonlinear parameters,” J. Soc. Ind. Appl. Math., vol. 11, no. 2, pp. 431-441, 1963.

G. Li Puma, A. Brucato, “Dimensionless analysis of slurry photocatalytic reactors using a two-flux and six-flux radiation absorption-scattering models,” Catal. Today, vol. 122, pp. 78-90, 2007.

G. Li Puma, B. Toepfer, A. Gora, “Photocatalytic oxidation of multicomponent systems of herbicides: Scale-up of laboratory kinetics rate data to plant scale,” Catal. Today, vol. 124, pp. 24-132, 2007.